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MultiGas NDUV Ultraviolett-Module

Beschreibung

The RITTER »MultiGas« UV sensor is the world’s first gas analysis module based on miniaturized UV-LEDs. The stability and lifetime of these UV-LEDs enables high-precision gas analyses down to the ppm range. By using two UV-LEDs two gases can be detected simultaneously. Furthermore, with this approach measuring ranges from ppm to Vol.-% can be realized.

In the spectral range from 200 nm to 500 nm, nitrogen oxides (NO + NO2), aromatic hydrocarbons, hydrogen sulphide, ozone, sulphur dioxide and chlorine can be reliably detected with this new sensor platform.

The entire unit can be disassembled for easy maintenance/service.

The individual internal modules are sealed by means of O-ring connections.

In order to achieve an optimum adaptation to the required measuring range, the lengths of the modular measurement cells (= cuvettes) can be implemented in the range of 5 mm (large measurement range in percentage level) up to 250 mm (small measurement range in ppm level).

Cuvettes with a length ≥ 20 mm are coated with a resistant gold layer in order to improve the reflection properties for low concentration level detection. Cuvettes used with aggressive gases are gold-coated as well.

The internal mechanical parts are made out of aluminium, optionally out of stainless steel.

For fast response applications the measuring system delivers a stable result within t90 ≈ 1-2 seconds.

Anwendungen

  • Biogas / natural gas analysis
  • Environmental and Process Measurement
  • TOC analysers
  • Continuous Emission Monitoring (CEM)
  • Elemental analysis
  • Industrial gas analysis

Specifications NDUV Sensor

HXXO20220804153226 2560

General features

Messverfahren: Innovative NDUV Sensor
(nicht-dispersiver UV-Sensor)
Detectable gases:
O3 CL2 H2S SO2 NO2
Number of simultaneously detectable gases:  max. 2
Measurement ranges: See below
Volumenstrom-Bereich: 1 ltr/d ~ 300 ltr/h – For higher flow rates the sensor can be operated in bypass
Max. gas inlet pressure: 300 mbar
Pressure loss (without additional optional sensors):  10 @ 100 / 35 @ 200 / 70 @ 300 (mbar @ ltr/h)
Temperature compensation:  Yes
Datenerfassungs-Software:  Yes
Lifetime of UV radiation source:  > 8 000 h
Measurement cuvette: Stainless steel with silicone coating inside
Cuvette sealing:  Viton O-ring
Gehäuse:  High-quality table-top casing, aluminium
Dimensions (W x H x L):  464 x 189 x 305 mm
Gewicht:  approx. 6.5+ kg
Gas connections:  PVDF screw-type tube connection for tube Øi 4mm, Øo 6 mm

Measuring response

Linearity error:  < ± 1% F.S.
Repeatability:  ± 0.5% F.S.
Long term stability zero N2 < ± 1% F.S. / 24h
Long term stability span:  < ± 1% F.S. / month
Temperature influence of zero point:  < 1% F.S. / 10K
Temperature influence of span: < 2% F.S. / 10K
Cross sensitivity: < 2% F.S.
Pressure influence:  < 1.5% / 10hPa of reading
Aufwärmzeit:  1 min (initial), <60 min for full specification
Ansprechzeit (t90): 1.5 – 15 sec
Sampling frequency by software:  ≤ 10 Hz
Detection limit:  See below
Resolution:  0.5 x detection limit

Electrical features

Spannungversorgung:  24 VDC inkl. Steckernetzteil 100 ~ 240 VAC / 24 VDC
Supply current (peak) <0.4 A
Average power consumption < 7.5 W
Schnittstelle: USB (standard), RS232 (option) – incl. data transmission cable 1 m
Analogue voltage output (option):  0-2V / 0-5V / 0-10V

Climatic conditions

Max. Betriebstemperatur:  +25 ~ +45 °C
Storage temperature:  –20 ~ +60 °C
Betriebsdruck:  800 ~ 1200 hPa (mbar)
Ambient humidity: 0 ~ 95% rel. humidity // Condensing inside of sensor must be prevented!

Specifications H2S Sensor

The H2S sensor works according to the principle of non-dispersive UV absorption (NDUV).

The measuring wavelength used is in the lower nanometer range, which enables inter-ference-free measurements with water vapour and hydrocarbons. This makes the sensor ideal for use in biogas measurements, as accompanying gases such as NH3, CO2, CH4 and H2O do not affect the accuracy of the measurements.

General features

Messverfahren:Innovative NDUV Sensor
(nicht-dispersiver UV-Sensor) Dual beam
Detectable gases:
H2S SO2
Number of simultaneously detectable gases:max. 2
Measurement ranges:See below
Volumenstrom-Bereich:6 ~ 300 ltr/h – For higher flow rates the sensor can be operated in bypass
Max. gas inlet pressure:300 mbar
Pressure loss (without additional optional sensors):10 @ 100 / 35 @ 200 / 70 @ 300 (mbar @ ltr/h)
Temperature compensation:Yes
Datenerfassungs-Software:Yes
Lifetime of UV radiation source:> 8 000 h
Measurement cuvette:Stainless steel with silicone coating inside
Cuvette sealing:Viton O-ring
Gehäuse:High-quality table-top casing, aluminium
Dimensions (W x H x L):464 x 189 x 305 mm
Gewicht: approx. 6.5+ kg
Gas connections:PVDF screw-type tube connection for tube Øi 4mm, Øo 6 mm

Measuring response

Linearity error:< ± 1% F.S.
Repeatability:± 0.5% F.S.
Long term stability zero N2:< ± 1% F.S. / 24h
Long term stability span:< ± 1% F.S. / month
Temperature influence of zero point:< 1% F.S. / 10K
Temperature influence of span:< 2% F.S. / 10K
Cross sensitivity:< 2% F.S.
Pressure influence:< 1.5% / 10hPa of reading
Aufwärmzeit:1 min (initial), < 15 min for full specification
Ansprechzeit (t90):1.5 – 15 sec
Sampling frequency by software:≤ 10 Hz
Detection limit:See below
Resolution:0.5 x detection limit

Electrical features

Spannungversorgung: 24 VDC inkl. Steckernetzteil 100 ~ 240 VAC / 24 VDC
Supply current (peak):<0.4 A
Average power consumption:< 7.5 W
Schnittstelle:USB (standard), RS232 (option) – incl. data transmission cable 1 m
Analogue voltage output (option): 0-2V / 0-5V / 0-10V

Climatic conditions

Max. Betriebstemperatur: +5 ~ +45 °C
Storage temperature: –20 ~ +60 °C
Betriebsdruck: 800 ~ 1200 hPa (mbar)
Ambient humidity:0 ~ 95% rel. humidity // Condensing inside of sensor must be prevented!

Specifications UVRAS Sensor

HXXO20220804153654 2560

Für den Nachweis von NO wird eine elektrodenlose Gasentladungslampe (EDL) eingesetzt. In der EDL wird N2 und O2 zu NO umgewandelt und erzeugt selektive UV-Strahlung. Mit dieser Strahlung wird eine querempfindlichkeitsfreie NO-Messung ermöglicht. Dieses Verfahren wird als UV-Resonanzspektroskopie (UVRAS) bezeichnet.

A combination of both the UVRAS and NDUV technology allows the simultaneous gas analysis of NO, NO2 and SO2 in the lower ppm range which is particularly important in flue gas analysis (Continuous Emission Monitoring, CEM).

General features

Messverfahren: Innovative NDIR Sensor (non-dispersive infrared sensor)
Detectable gases: 
SO2 NO2 NO
Number of simultaneously detectable gases: max. 3 per sensor unit
Measurement ranges: See below
Volumenstrom-Bereich: 1 ltr/d ~ 300 ltr/h – For higher flow rates the sensor can be operated in bypass
Max. gas inlet pressure: 300 mbar
Pressure loss (without additional optional sensors): 10 @ 100 / 35 @ 200 / 70 @ 300 (mbar @ ltr/h)
Temperature compensation: Yes
Datenerfassungs-Software: Yes
Lifetime of IR radiation source:> 40 000 h
Measurement cuvette: Aluminium, with measurement ranges ≤1% gold-plated inside
Cuvette sealing: Viton O-ring
Gehäuse: High-quality table-top casing, aluminium
Dimensions (W x H x L): 171 x 86 x 290 mm
Gewicht: approx. 2 kg
Gas connections: PVDF screw-type tube connection for tube Øi 4mm, Øo 6 mm

Measuring response

Linearity error: < ± 1% F.S.
Repeatability: ± 0.5 % F.S.
Long term stability zero N2: < 3 ppm / 24h
Long term stability span: < ± 1 % F.S. / month
Temperature influence of zero point: < 1 % F.S. / 10 K
Temperature influence of span: < 2 % F.S. / 10 K
Cross sensitivity:
  • 500 ppm NO2 < 2 ppm
  • 100 ppm SO2 < 2 ppm
  • 100 ppm N2O < 10 ppm
  • 20 °C D.P. H2O < 10 ppm
Pressure influence:  < 1.5% / 10 hPa of reading
Aufwärmzeit:  1 min (initial), < 60 min for full specification
Ansprechzeit (t90):  1.5 ~ 15 sec
Sampling frequency by software:  ≤ 10 Hz
Detection limit:  See below
Resolution:  0.5 x detection limit

Electrical features

Spannungversorgung:  24 VDC inkl. Steckernetzteil 100 ~ 240 VAC / 24 VDC
Supply current (peak):  1.5 A
Inrush current:  0.2 ~ 0.7 A
Power consumption:  36 W
Schnittstelle:  USB (standard), RS232 (option) – incl. data transmission cable 1 m
Analogue voltage output (option):  0-2V / 0-5V / 0-10V

Climatic conditions

Max. Betriebstemperatur: +5 ~ +40 °C
Storage temperature:  –20 ~ +60 °C
Betriebsdruck:  800 ~ 1200 hPa (mbar)
Ambient humidity: 0 ~ 95% rel. humidity // Condensing inside of sensor must be prevented!

Tabelle der Messbereiche

Messbereiche / Messbereichs-Endwert (F.S.)
100 Vol.% 50 Vol.% 30 Vol.% 20 Vol.% 10 Vol.% 5 Vol.% 1 Vol.% 5.000 ppm 2.000 ppm 1.000 ppm 500 ppm 300 ppm 100 ppm 50 ppm 10 ppm
O3
CL2
H2S
SO2
NO2
NO

Infrarot-Modul NDIR Ultraviolett-Modul NDUV Ultraviolett-Modul NDUV / UVRAS

* Kalibrierung mit Propan

(1) Full Scale (FS)

Other ranges on request

Table of Detection Limits (= 3 σ) in Percent of Full Scale

Nachweisgrenzen / % vom Messbereichs-Endwert (F.S.)
100 Vol.% 50 Vol.% 30 Vol.% 20 Vol.% 10 Vol.% 5 Vol.% 1 Vol.% 5.000 ppm 2.000 ppm 1.000 ppm 500 ppm 300 ppm 100 ppm 50 ppm 10 ppm
O3 < 0,1% < 0,1% < 0,1% < 0,2% < 0,5% < 0,5% < 0,5%
CL2 < 0,1% < 0,1% < 0,1% < 0,1% < 0,1% < 0,1% < 0,1% < 0,2% < 0,5%
H2S < 0,1% < 0,1% < 0,1% < 0,1% < 0,2% < 0,5%
SO2 < 0,1% < 0,1% < 0,1% < 0,1% < 0,1% < 0,1% < 0,1% < 0,1% < 0,5% < 0,5% < 0,5%
NO2 < 0,1% < 0,1% < 0,1% < 0,2% < 0,2% < 0,5% < 0,5% < 0,5%
NO < 0,1% < 0,1% < 0,1% < 0,2% < 0,2%

Infrarot-Modul NDIR Ultraviolett-Modul NDUV Ultraviolett-Modul NDUV / UVRAS

* Kalibrierung mit Propan

Definition der Nachweisgrenze

Die Nachweisgrenze ist der kleinste Messwert, der mit einer bestimmten Unsicherheit ermittelt werden kann. Diese Unsicherheit beinhaltet die Auflösung, das Rauschen und die Stabilität des Gassensors für ein bestimmtes Gas und einen bestimmten Messbereich. Zur Ermittlung der Nachweisgrenze werden mehrere Einzelmessungen unter identischen Messbedingungen durchgeführt. Mit den erhaltenen Werten der Einzelmessungen wird die Standardabweichung "Sigma" (σ) berechnet. Die in der Tabelle angegebenen Werte entsprechen dem dreifachen Betrag von Sigma.

1) Zero to Full Scale (FS)

Recalibrations

The following recalibration intervals are recommended for UV sensors:

  • Zero-point:
    • Concentrations < 300 ppm: Every 48 hours with inertgas, e.g. Nitrogen
    • Concentrations ≥ 300 ppm: Every 24 hours with inertgas, e.g. Nitrogen
  • End-point (full scale): Every 3 months with suitable calibration gas